Ionic compounds have strong electrostatic attractions between oppositely charged ions in this?

Ionic compounds have strong electrostatic attractions between oppositely charged ions in this?

  • Correct Answer: occasional array
  • incorrect array
  • normal array
  • regular array

Explanation: Ionic compounds have strong electrostatic attractions between oppositely charged ions in a regular array. The lattice energy (U) of an ionic substance is defined as the energy required to dissociate the solid into gaseous ions; U can be calculated from the charges on the ions, the arrangement of the ions in the solid, and the internuclear distance. Because U depends on the product of the ionic charges, substances with dior tripositive cations and/or di- or trinegative anions tend to have higher lattice energies than their singly charged counterparts. Higher lattice energies typically result in higher melting points and increased hardnessbecause more thermal energy is needed to overcome the forces that hold the ions together. Lattice energies cannot be measured directly but are obtained from a thermochemical cycle called the Born–Haber cycle, in which Hess’s law is used to calculate the lattice energy from the measured enthalpy of formation of the ionic compound, along with other thermochemical data. The Born–Haber cycle can be used to predict which ionic compounds are likely to form. Sublimation, the conversion of a solid directly to a gas, has an accompanying enthalpy change called the enthalpy of sublimation.

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